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Similar comparisons using basic metals, such as the alkali and alkaline earths, which should enhance selectivity for insertion of CO over hydrogenation, increased the selectivity for the hydroformylation over hydrogenation as expected, although catalytic activity was reduced.
Several derivatives were found to enhance selectivity for Gram-positive cocci (SKI-4 and SKI-10) but had minimal activity against Klebsiella, Pseudomonas, and Candida (Supporting Information Table 1).
Similar(58)
I209A also demonstrated enhanced selectivity for testosterone 16β-hydroxylation over 16α-hydroxylation.
Furthermore, the highly enhanced selectivity for hydrogen was also achieved through filtration action of chitosan for large size and polar molecules.
However, we consider an operation that enhances selectivity for small, dark targets.
This work was extended to petroleomics studies, where carbon dioxide exhibited enhanced selectivity for separating the polar constituents of crude petroleum.
Increasing FT predicted enhanced selectivity for positive compared with negatively valenced facial cues in reward-related regions such as caudate, putamen, and nucleus accumbens but not the amygdala.
Chemical modifications to the cilengitide molecule, including N-methylation at distinct positions, can modulate its biological, structural, and pharmacokinetic properties; this could enhance selectivity, particularly for the αv β3 subtype [ 77].
These crystal structures provide a framework for further ligand development of the naphthalene diimide series to enhance selectivity and affinity.
Basic conditions and moderate temperature (40 °C) represent a good compromise for enhancing selectivity to aminoacids.
Judicious choice of functional groups for the diazonium salts enable enhanced selectivity and specificity in sensing applications.
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