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In addition, the end of polymer chains on silicon substrate contains selenium element which may be useful in biosensor applications.
Prof de With and his team found that by attaching these molecules on the end of polymer "stalks" and mixing these throughout the coating, any that are removed by scratches are replaced by a new, self-orientating layer.
The recovery was 12% at the end of water pre-flush, 46% at the end of polymer flood, and 59% at the end of the post flush (Koning et al. 1988).
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It seems the reaction occurred at the end of polymers or defect areas with terephthalate groups at the end.
Due to the increase of the polymer chain length and the polymer concentration, interaction between the nonreducing end of the polymer chains and the enzyme become more difficult in time.
The end effects of polymer chains and effects of solid wall confinement are also considered.
Chemical PHB degradation may occur either randomly in the middle of the polymer chain or from the end of the polymer chain.
This alkoxyamine was exploited following two strategies: (i) a post-functionalization approach based on the transformation of α-NHS chain ends of polymers previously obtained by nitroxide mediated polymerization (NMP) from 1 (path A) and (ii) a pre-functionalization approach based on the functionalization of alkoxyamine 1 prior to NMP (path B).
Like other flagellated bacteria, the body of Pseudomonas flagellum consists of a mass of protofilaments, end-to-end polymer of a single protein, flagellin [4].
Therefore, it may seem surprising that the anti-PEG antibodies display so much higher affinities for the small group at the end of the polymer than for the large number of oxyethylene units (CH2 CH2 O) within the polymer backbone (c. 227 for 10 kDa PEGs).
Another advantage of a controlled polymerization is the possibility to introduce specific functional groups, either at the beginning of each polymer chain by the use of an external initiator, or at the end of the polymer chain using an endcapper.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com