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TGA experiments show that the temperature, film thickness, and the eliminated group play an important role on the diffusion and evaporation of the elimination products.
Water and elimination products released during the elimination reaction act as plasticizers and lower the Tg.
The elimination products can further decompose and interact with the conjugated system to form undesirable crosslinks (network formation) in a temperature range of 140 160 °C.
In the presence and absence of H2O molecule, different reactions may proceed and hydrolysis and elimination products on the surfaces of Zn2+ as Lewis acid sites will be revealed.
The elimination process of n-alkyl-sulphinyl precursor polymers towards conjugated poly[2- 3′,7′-dimethyloctyloxy -5-methoxy-1,4-phenylene vinylene], or OC1C10-poly[2- 3′,7′-dimethyloctyloxy -5-methoxy-1,4-phenylenel scanning calorimetry (MTDSC) and thermogravimetric analysis (TGA), with a focus on the subsequent reactions of the elimination poly[2- 3′,7′-dimethyloctyloxy -5-methoxy-1,4-phenylene
26a, 56 Few of them were soluble in THF, toluene or CH3CN, but they provided considerable amounts of elimination products because of their strong Brønsted basicity.
Similar(52)
Upon treatment with base, HCl was eliminated from the molecule (Scheme 1).[ 2] The observed elimination product was O, O-dimethyl O-2,2-dichlorovinyl phosphate (2), also known as DDVP.
The results showed 1 a as the only elimination product, HDO being expelled during the elimination process.
The formation of thermodynamically more stable alkene 12 as the only observed elimination product suggests that the latter process predominates.
In fact, the only organic product observed in GC was the β-hydride elimination product 5, which was not even observed under stoichiometric conditions.
The crude product was measured by NMR and GC-MS which showed the elimination product was 3-methylfuran-2 5 H)-one (1 a).
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