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As would be expected, given the electronic impact of electron withdrawing fluorine adjacent to an acetal centre, sugar nucleotides bearing a fluorine atom at either the 2 or 5 position of the sugar ring do not generally serve as glycosyltransferase substrates, but they are effective competitive inhibitors of such enzymes.
The following year, 1977, saw the full electronic impact of Donna Summer's I Feel Love and Kraftwerk's Trans-Europe Express.
MS ionization: electronic impact at 70 eV.
The mass spectra resulting from ionization by electronic impact (EI-LRMS) were acquired on a 5973 Network MSD (Agilent).
The ionization was created by an electronic impact at 200 °C, while the transfer line was kept at 250 °C.
The results show that the proposed electronic impact oscillator is in agreement with the mechanical impact oscillator.
Similar(48)
We injected 1 µl of each FAME solution in an Agilent Technologies 6890N GC Network System with a 7683 series injector and coupled to an electronic impact-mass spectrometry detector (EI-MS; 5973N MSD; Agilent Technologies).
These observations provide valuable insights into the molecular engineering methodology based on fine tuning structural-electronic impact of electron-donating antenna in efficient ruthenium sensitizers.
We report a systematic research to understand the structural-electronic impact of the arylamine electron-donating antennas on the performances of the ruthenium complexes for dye-sensitized solar cells.
The UV Vis absorption, electrochemical measurement, incident photon-to-current conversion efficiency and transient absorption spectra confirm that the excellent performance of RC-36 is induced by synergistically structural-electronic impacts from enhanced absorption capacity and well-tuned electronic characteristics.
Structural as well as chemical and electronic changes impact the NEXAFS spectra, with variation of the C N bond length influencing the energy of the σ*C N resonance relative to the IP, thereby providing access to bond length determination of solutes in solution by comparison with NEXAFS data of PABA species in the solid state.
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