Sentence examples for electronic factors from inspiring English sources

The reactions of phenol 3 with methyl-substituted salts 1 are influenced by both electronic and ortho effects, whereas only electronic factors are important with more electron-rich methoxy salts 2. The selectivities that were obtained with aniline 6 were rather different from those with phenol 3, as only the electronic properties influenced the outcome and phenylation was always the major pathway.

This research added to a growing body of knowledge that suggested that molecular-scale electronics systems would need to account for heat conduction in addition to electronic factors.

For transition metal ions, electronic factors also have an important influence on rates of substitution.

An alternative approach to the problem of surface catalysis involves the consideration of electronic factors in catalyst and reactants.

For more ionic (also called outer-orbital) complexes, such as fluoro or aqua complexes, electronic factors are less important in determining coordination numbers, and configurations corresponding to more than 18 valence electrons are not uncommon.

The coordination number of a particular complex is determined by the relative sizes of the metal atom and the ligands, by spatial (steric) constraints governing the shapes (conformations) of polydentate ligands, and by electronic factors, most notably the of the metal ion.

The increase in Cu…Cu distance and Cu-N distance in systems containing substituted pyrimidine ligands 3,4 may be due to steric and electronic factor of the apical ligand.

These results indicate that the electronic factor may also play an important role, in addition to the atomic size rule, in determining the alloying behavior and the defect structure/mechanism of C15 Laves phases based on NbCr2.

The results obtained indicate that the antibacterial activity of the 3-aryloxazolidin-2-ones is strongly dependent on electronic factor as expressed by lowest unoccupied molecular orbital energy (LUMO), spatial factor as expressed by density and thermodynamic factors accounted for by molar refractivity and heat of formation.

It occupies a wide frequency range and is affected by various electronic and non-electronic factors, especially narrow-band radio noise from civilian broadcasts.

To provide low noise with highest electronic amplification factors, a bioamplifier with headstage system (DAM80, World Precision Instruments, Berlin, Germany) was used (settings: 10 000, low filter of 300 Hz and high filter of 3 kHz).