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Based on the measurement data, we analyzed the ratio of ionic current density to electronic current density in the temperature range of 550 900 °C.
Finally, we demonstrate that keto-defects on the fluorene moiety of the F8BT phase, induced by photo-oxidation, causes a simultaneous increase of the intra-chain contribution and decrease of the inter-chain contribution to the electronic current density, whereas in the reduced form the difference between both contributions is significantly smaller.
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The electron current density (mA/cm2).
This leads to a system of coupled equations that computes the electromagnetic field, the nuclear positions, and the electronic current and charge densities simultaneously.
The examined parameters include the thickness, effective electronic and ionic conductivities, exchange current density, operating temperature, output current density, electrode- and electrolyte-particle radii, composition and porosity of the cathode inter-layer.
It is theoretically shown that the interfacial oxygen partial pressure which is an important designing variable, is dependent primarily on the oxygen partial pressure gradient across the IC, the low level oxygen conductivities of the two layers and is largely independent of their electronic conductivities and the total current density through the IC material.
It is found that both the dimensionless electronic and ionic current densities remain constant with respective values of one and zero for most part of the anode before started to vary towards the end of the anode.
To deeply analyze the electron-blocking effect and optimize the thickness ratio of the BCS layer, electronic conductivities, leakage current densities and cell efficiencies considering the internal shorting and polarization are calculated by a mathematic model.
Polymer films grown using low current density show higher electronic conductivity and increased crystallinity.
Moreover, electronic transport properties including the transmission spectra, current density and transmission eigenvalues can also be obtained using DFT when utilized in conjunction with non-equilibrium Green's function (NEGF) formalism [48].
In porous electrodes, the current density of the conversion of electronic current into ionic current is not everywhere uniform.
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