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Further photoelectrochemical investigations through incident photon-to-current efficiency and electrochemical impedance spectra showed that the all-nano-TiO2 compact layer acts as contact layers that increase the electron harvesting in the external circuit, enhancing efficiencies up to 50%.
However, the yield of electron harvesting could be improved by as much as 4.5-fold simply by changing the nanostructure of the anode surface.
Furthermore, the yield of electrogenic activity appears to be underestimated because dissolved oxygen can react with electrons and protons to form water thereby interfering with electron harvesting by extracellular acceptors.
The yield of electrons harvested by extracellular electron acceptor to photons available for photosynthesis ranged from 0.05% to 0.3%, although the efficiency of electron harvesting likely varies depending on terminal electron acceptor.
The relatively low yield of electron harvesting by extracellular acceptors observed in our experiments was in part due to high amounts of dissolved oxygen present at concentrations substantially exceeding those found in natural cyanobacterial mats.
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Recently, the photosynthetic electron transfer chain is considered as a source of the electrons harvested on the anode surface, which is different from the previously designed anaerobic MFCs, sediment MFCs or anaerobic photosynthetic MFCs [70].
To calculate the number of anode electrons harvested, the recorded voltage curves for each genera were converted to amps of current using Ohm's Law (I = V/R).
By measuring the amount of electrons passing through the electrical circuits of MFCs under well controlled illumination conditions, it was possible to estimate the apparent yield of electrons harvested by the MFC anodes to the photons available for photosynthesis for each culture (Table 2).
The photoreduction was further enhanced by a factor of 5.5 in a system prepared by co-adsorbing ZnTCPP (5) as a light- and electron-harvesting moiety and the dyad ZnDMCPP-Re(bpy)(NHAc) (1) as a catalytic moiety on NiO, as a promising example of the design of a CO2 photoreduction system as the reduction terminal end of an artificial photosynthetic system.
While, in general, the yield of electron discharge appeared to be quite low, we found that it could be substantially increased by improving the design of the electron-harvesting system [15].
The intrinsic causes for varying short-circuit photocurrent density (Jsc) and open-circuit photovoltage (Voc) have been systematically investigated on the dyes and dye/(TiO2 38 systems including the conduction band energy shift, electronic structures, light harvesting efficiency, electron injection driving force, electronic coupling, dye regeneration driving force and so on.
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electron acquisition
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electron lifetime
electron mobility
electron beam
electron luminescence
electron volt
electron microscope
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