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The influencing parameters are voltage, tool feed rate and electrolyte discharge rate with mixing levels.
The high influence of the electrolyte was attributed to an addition of three factors: oxide generation, doping process, and electrolyte discharge.
A lower initial pH hinders water oxidation, favouring monomer oxidation and electrolyte discharge: the induction time decreases and the polymerization rate increases.
The increase of the temperature favours monomer oxidation and electrolyte discharge at the expense of water oxidation: the induction time decreases.
Similar(56)
In non-aqueous electrolytes, discharge oxides are usually insoluble and hence precipitate at local reaction site, raising the oxygen transport resistance in the pore network.
Li ions are intercalated and deintercalated between graphite and LiCoO2 through the electrolyte during discharge and charge.
However, for the electrode in EDA-free electrolyte, its discharge capacity is sharply decreased to only 138.5 m Ah g−1 after 100 cycles.
The cells with RGO-AQ used as cathode materials initially discharged 126 mA h/g when cycled between 1.8 and 3.2 V at the rate of 5.35 mA/g in LiPF6/EC:DEC (1 1) electrolyte, and discharged 185.7 mA h/g when cycled between 1.3 and 3.6 V against Li metal at the rate of 6.0 mA/g in LiClO4/PC electrolyte.
When discharging at 10 mA g−1 in 0.2 mol dm−3 MgCl2 aqueous electrolyte, the initial discharge capacity reaches 300 mAh g−1.
In the case of PPy pTS/PPy IC (polymer electrolyte), the reversible discharge capacity after 50 cycles was 16 mAh g−1, 76% of the intial discharge capacity.
The lithium polymer cell assembled with the stable gel polymer electrolyte delivered a discharge capacity of 134.3 mAh g−1 at ambient temperature and exhibited good capacity retention.
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