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6h On the other hand, the ortho effect has been rationalized by the bulkiest aryl group occupying the equatorial position in the T-shaped intermediate, because this position is less crowded than the apical position.
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This barrier of inversion is lower than for the related N-sulfonyloxaziridines, which has been rationalized as the effect of a stronger conjugative interaction between nitrogen and phosphorus than between nitrogen and sulfur in the transition state for epimerization.
This shift in absorbance is well-known and has been rationalized by the so-called polaritonic effect caused by a phase retardation of the electromagnetic waves (also known as extrinsic or electrodynamic effect) [13].
The conformational behaviour of the molecules has been rationalized by DFT calculations.
Support for Trump has been rationalized as not being about race the same way support for the Confederate flag was long rationalized.
The stereoselective formation of enolates has been rationalized with the Ireland model, although its validity is somewhat questionable.
The observed effects of the mutations have been rationalized on the basis of an existing structural model of CPS1.
This is relevant since overexpression of wild-type NADH ubiquinone oxidoreductases usually correlates with negative, sometimes detrimental effects for the cells, which have been rationalized by cellular stress associated with overexpression of integral membrane proteins [ 12].
The findings have been rationalized in terms of theoretical results for the effect of imperfections on the energy release rate.
Stanley Kubrick? "His faults have been rationalized as virtues".
Costs have been rationalized.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com