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The reduction of Ni(+2) species, less easy than that of Pd(+2) species commonly used in the authors' laboratory in the case of the tin-free process, was performed in the present work either using a chemical path or by plasma treatment in a non-oxidizing atmosphere (H2 or Ar), then checked by XPS.
The calculated functionalization energies are 0.14, 3.19, 0.57, 1.72, 2.69, 2.11 and 4.05 eV for Ti, Cr, Mn, Fe, Co, Ni, and W, respectively (see Table 1), indicating that the functionalization of Ti is relatively easy than that of other elements because of the lower formation energy.
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