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Their macroscopic responses are directly attributed to the nature of each dynamic bond.
We predict that this forthright dynamic bond archetype fabrication can improve the self-healing efficiency of hydrogels with enhanced mechanical properties.
A large number of polymer materials bearing dynamic bond systems have been reported, while the focus is mainly on the macroscopic properties such as self-healing and shape memory.
With the aim of fostering a dynamic bond with your baby, examining your internal landscape during the prenatal phase can yield increased clarity and space for connecting with this new addition to your family.
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"These dynamic bonds allow the material to self-heal," said Chao Wang, another member of the research team.
It is well established that dynamic bonds have significant effect on the performance of polymers.
The incorporation of dynamic bonds into polymer structures has endowed polymers with structurally reorganizable properties and stimuli-responsiveness.
Polymers with dynamic bonds are able to self-heal their fractured interfaces and restore the mechanical strengths.
The resulting material is linked via reversible ion dipole interactions, an approach that is in contrast to the dynamic bonds typically used to build self-healing materials: namely, hydrogen bonds and metal ligand coordination.
Here, we take a self-healable nanocomposite hydrogel as an example to illustrate an interfacial self-healing theory for hydrogels with dynamic bonds.
Formation of dynamic bonds evolves simultaneous breaking and reconnecting between the ester and hydroxyl groups, which means the total number of the covalent bonds maintains the same (see Fig. 1f, g, Supplementary Note 2 and Supplementary Fig. 2), while the crosslinking density continues increasing until the reaction reaches dynamic equilibrium31 (see Supplementary Note 3 and Supplementary Fig. 3).
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