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Platinum (Pt) and Pt-based materials were mainly utilized in the fuel cell as the catalysts due to the fact that they were considered as the most effective electrocatalysts for ORR [4, 5], but high cost of Pt and low durability of support materials such as carbon particle prevent the practical commercialization [6].
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As is known, the catalytic activity and durability of supported catalyst are strongly dependent on the morphology of supporting material and the size distribution of metal nanoparticles (NPs).
However, excessive amount of oxygen-containing functional groups can reduce the electrical conductivity and electrochemical stability of CNT and graphene, which can make them weak to chemical oxidation and thus deteriorate the long-term durability of supported electrocatalysts [18].
Isotopic exchange reaction between CH4 and CD4 showed that the dissociation of methane was significantly retarded by supporting Mo2C on ZrO2, which could be the main reason of high activity and durability of supported catalysts.
Silica monolith columns are characterized by mechanical durability of the support and low backpressure of the substrate solution flowing through a macroporous structured support, as compared with conventional packed beds.
We report the impact of oxygen functionalization of carbon black (CB) supports on the activity and durability of CB supported Pt catalysts for the ORR.
The correlation between internal chemical potential, and durability of anode-supported BCY (BaCe0.85Y0.15O3-δ) electrolyte cells, was investigated as a function of electrolyte thickness.
The observational nature of the existing evidence for home haemodialysis together with the concerns that clinicians raise over the safety and durability of home haemodialysis support the need for a randomised trial evaluating the effectiveness and safety of home haemodialysis.
Cyclic voltammetry, chronoamperometry and electrochemical impedance techniques were carried out to evaluate the methanol electrocatalytic oxidation activity and durability of Pt catalysts supported on the nitrogen doped graphene.
"The higher their capability the more they can lobby for the removal of sanctions and even extract concessions of support and durability".
Moreover, nitrogen doping improves the durability of the resultant carbon support catalysts because of the enhanced π bonding [24,25] and the basic properties due to the strong electron donor behavior of nitrogen atoms [26].
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