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Furthermore, fibers can display a nanoporous ultrastructure due to solvent evaporation.
Conventionally, the contribution of apolar desolvation to affinity is attributed to gain of entropy due to solvent release.
Changes in intermolecular arrangements, stoichiometry, and hydrogen-bonding interactions of solvatomorphs were due to solvent incorporation to solvates.
For example, heat effects due to solvent sorption, errors introduced due to concentration dependent diffusion coefficients and swelling are unavoidable.
There are two main barriers for the PCC process using solvent to be commercially deployed: (a) high capital cost; (b) high thermal efficiency penalty due to solvent regeneration.
The Raman signal due to solvent molecules was found to influence the synchronous profile of a fluorophore to different extents at different Δλs.
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We report the fabrication of drug-eluting microfibers where drug loading and processing conditions alone increase microfiber strength and stability partially due to solvent-induced crystallization.
This may be due to solvent-induced loss of white matter volume throughout the brain (Rosenberg et al, 1988) with a particularly high level of white matter abnormalities found in the frontal and temporal lobes (Yücel et al, 2010), regions that are critical mediators of higher-order cognitive tasks (Curtis and D'Esposito, 2003; Curtis and Lee, 2010; Dalley et al, 2004).
We do not know, however, whether these species are monomers; however, the fact that they elute at larger volumes than the corresponding folded TRX, suggests protein-column interactions, probably due to solvent-exposure of hydrophobic residues (which is further confirmed by ANS-binding experiments), and then, the possibility of aggregation to bury those solvent-exposed hydrophobic patches.
This was due to solvents from the TiO x precursor damaging the perovskite layer during deposition.
The enhancement of enzyme activity due to solvents could be attributed to lipase disaggregation, some structural changes in the enzymes (maintaining the lipase on its open conformation), and even modification at the oil-water interface to facilitate enzymatic action [ 57].
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