Changes of the double layer properties at lower frequency would be more dramatic than the changes in the solution resistance at the higher frequency region.
The dependence of the double layer properties of tatraalkylammonium cations on the electrode material confirmed this suggestion.
Published data and the results of authors' investigations of the electrical double layer properties in silver ion conducting solid electrolytes are discussed.
The frozen electrolyte technique (FREECE technique) allows one to investigate double layer properties in liquid and frozen electrolytes and in a wide range of temperatures.
From the experimental evidence, this Letter discusses the effects of the fundamental material properties, including Young modulus and electrical double layer properties, on actuation performance of the resultant actuators.
The significance of the present results is discussed with respect to the effect of alkali cation nature on double layer properties at negative charge density, and on the reduction of the proton at mercury in the same potential region.
In the case of metallic electrodes (Pt,Au) it was found that double layer properties are strongly influenced by the electrode nature; it means that the specific absorption of electrolyte ions plays the essential part.
The double layer properties of a series of metal electrodes and CO-covered Pt electrode, such as the potential of zero charge and the differential capacitance, are calculated from theory and a good agreement between theoretical values and experimental data is achieved.
Electric double layer properties of variously treated Bi, Sb and Cd electrodes were studied in terms of the Debye length dependent roughness theory, recently developed by Daikhin et al. The geometrical roughness factor, root mean square departure of the surface from flatness, height of surface roughness and the medium lateral correlation length values have been obtained.
Influence of the surface structure of electrodes on the electric double layer properties, as well as on the adsorption characteristics of various organic compounds has been investigated by cyclic voltammetry, impedance and electron microscopic methods at variously prepared Bi, Sb and Cd electrodes.
It is shown that the structure of the zinc deposits is controlled by double layer properties and it is proposed that the brightening effect of ethylene diamine and ammonia are caused by their ability to inhibit the adsorption of chloride at the electrode surface.
