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In this study, respective equilibrium quotients are recalculated according to the B dot equation.
In the work of Seward [41], log was calculated by using the B dot equation.
In addition, solubility quotients of brucite are also predicted by using the B dot equation [9] for comparison (Figure 4).
Therefore, the SIT model performs better than the B dot equation does even in the ionic strength range valid for the B dot equation, although the B dot equation does have the general applicability as it does not require any specific interaction coefficients.
In the study of Seward [41], equilibrium constants such as K°s0 were extrapolated to infinite dilution by using the B dot equation [9], and equilibrium quotients (conditional equilibrium constants) were not presented.
In using the B dot equation, the ion size parameters for Mg2+ and H+ are from the compilation of Wolery [10], and B dot parameters are from Helgeson [9].
Similar(50)
The B-dot equation was used for the aqueous species activity coefficient model.
The use of the B-dot equation typically yields brines with slightly higher solution pH (≈ 0.1 pH units).
However, it is generally recognized that the B-dot equation becomes increasing less accurate at I > 0.5 molal.
The B-dot equation is an extended form of the Debye-Huckel equation and was used in this study because it can be applied to NaCl based solutions with high ionic strengths (3 molal) over a wide range of temperature.
Despite these limitations, we chose to use B-dot equation to correction for species activity because the Pitzer equations are lacking for many elements at temperatures above 25°C.
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