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electrical conductivity of these doped films was measured as a function of the doping time and as a function of the temperature between 80 and 300 K. Compared with the maximum conductivity obtained in unstretched PPV films doped with FeCl3 (σdc = 35 Ω−1cm−1), the stretched a higher conductivity (σdc = 230 Ω−1cm−1) when measured along the stretching orientation.
The dopant uptake is a complicated function of the ion mass, ion fluence and the doping time.
The junction depth is about 10 nm with the HWCVD doping time of 25 min [27].
For doping time less than 20 s, the surface potential was monotonically increased to about 0.5 V [13].
According to these results, increasing of the conductivity values of polymers were observed as connected iodine doping time.
This process cannot bring any defects for SCNT [30, 31]. Figure 4 Raman spectra of pristine and different doping time of SCNT.
Slower processes, represented by the other semicircles, are observed at lower current doping (time constants of order of 10-1 s), while an acceleration of them is observed at higher current (time constants in the order of ms).
The ID/IG values of SCNT for different doping time calculated from the Raman spectrum as shown in Figure 3 are almost about of 0.70, although the intensities of ID and IG were decreased.
For a better understanding of the electrochemical doping, time dependent potentiostatic experiments with different maximum achieved potentials were performed.
