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In addition to the expected elongation of all of the M=X bonds (Table S1) and the even greater distortion from ideal octahedral coordination angles at the metal center (see above), the O1⋅⋅⋅O21 phenoxide⋅⋅⋅phenoxide separation is markedly increased (3.074(4), 3.107 9), 3.154, 3.603 5), and 3.354 5) Å, measured for 1, 2, A (yttrium analogue),[ 8c] 3 A, and 3 B, respectively).
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Simulations permit one to examine distortions from ideal profile geometry due to flip angle and spin-lattice relaxation effects.
As the scan rate increases, slight distortion from the ideal symmetrical rectangle shape can be observed from the CV curves for both samples.
Both the ionic size and cation electronic configurations (e.g. bond-types) affect the structural distortion from the ideal fluorite structure and thus the response of pyrochlore-structure types to ion beam irradiation.
As the distortion from the ideal perovskite structure increases, G also increases from 0.15 vu for PrCoO3, to 0.205 vu for LuCoO3, in agreement with the increased difficulty in synthesizing the Tm3+, Yb3+, and Lu3+ members.
More pronounced distortion effects and deviations from ideal capacitive behavior have been observed at higher applied potentials (3.2 V) when the addition of AN in the electrolyte of EDLC is higher than 3.3 wt%.
The extent to which nearly degenerate bands are dispersed depends on the distortion of the selenate ion from ideal T d symmetry.
The existing law is far from ideal.
But it's far from ideal.
But it is still far from ideal.
The old system was far from ideal.
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