Sentence examples for distorted coordination from inspiring English sources

All ligands coordinated with molybdenum ion are inorganic ligands and the coordination adopts a distorted coordination sphere [1] (Fig. 1).

The results reveal that the central cadmium II) atom in the complexes was coordinated by two iodide ions and two nitrogen atoms from L1, L2, forming a distorted coordination geometry.

In the mesoporous systems, the partly amorphous character of the pore wall is correlated with the redox behaviour and coordination of incorporated iron; larger portion of iron may take part in Fe3+ ↔ Fe2+ reversible processes and Fe2+ may be stabilized in distorted coordination (not appearing in microporous structures).

The first reaction step differs however as Atkins and coworkers propose that the presence of layer Mn3+ leads to layer kinking, owing to their Jahn Teller distorted coordination sphere.

The origin of the unique photocatalytic activities of TiO2 nanoparticles comparing to the bulk is found in larger surface area and the existence of surface sites with distorted coordination.

This supports the hypothesis of Mn3+ atoms (that have a larger distorted coordination octahedron) segregation in the walls whereas Mn4+ atoms are mainly present in tunnel floors and ceilings.

The asymmetric unit consists of a cobalt ion with distorted octahedral coordination geometry, coordinated to two furfuryladenine cations and two chloride ions equatorially, a chloride ion and a water molecule axially (Figure 4). Figure 4 An ORTEP view of (4) showing the atom labelling scheme.

The structure of [GaCl(L)]⋅2 H2O shows a distorted octahedral coordination environment at gallium through pentadentate coordination of L2− by its N3O2 donor set and one chloride ligand.

In 1, the CuII ions are also six coordinate, but in Jahn Teller distorted {CuN4O2} coordination geometries (Cu-N, ≈2 Å) with the O-Cu-O vector (Cu-O, ≈2.31 2.58 Å) describing the elongated axis ${\left {d_{z2 } } \right)}$, perpendicular to the equatorial CuN4 plane ${\left {d_{x2 -y22 } } \right)}$ in the face of the cube.

The monoclinic baddeleyite structure (m-ZrO2) is thermodynamically stable under ambient conditions, where Zr atoms are in a distorted sevenfold coordination, and O atoms have four- or three-fold coordination.

Each of the BTA ligands provides two donor N atoms to coordinate to the Cu II) ions, exhibiting a distorted tetrahedron coordination geometry (Additional file 1: Figure S1).