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Resins used for water treatment should last for many years, but their life may be shortened either by accumulation of colloidal matter (prevented by adding activated carbon filters) or by oxidation caused by the dissolved chlorine in the water.
Reduction of dissolved chlorine at a Pt rotating disc electrode exhibited mass transport controlled behaviour, in agreement with Levich's equation over the potential range 0.3 0.9 V (SHE).
In this study, we tested new microencapsulated chemicals, along with the traditional dissolved chlorine and KCl, as alternatives to control L. fortunei infestation in industrial and water supply plants along rivers.
Metals such as Ag, Au, Cu, Pb, Pd, Sn, etc. are dissolved from shredded WEEE in an acidic aqueous chloride electrolyte by oxidizing them with aqueous dissolved chlorine species.
This could form the basis of a linear sensor, possibly using a microelectrode for measurement and control of the dissolved chlorine concentration in the efflux of leach reactors and inlet to cathodes of the electrowinning reactors, in the envisaged process.
Since the reaction rate is very highly dependent on the concentration of dissolved chlorine, bulk mixing of the jet on entering the receiver effectively 'freezes' the reaction and enables experimental determination of the ratio.
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The underlying chemistry was thoroughly investigated and it is found that the formation of nanoflower is synergistically caused by dissolved oxygen, chlorine ions and phosphate ions.
The time evolution of chlorine-related species (i.e., active chlorine (dissolved Cl2, HClO, OCl−), chlorite, chlorine dioxide, chlorate and perchlorate) was investigated in order to establish whether their formation and consumption was related to either chemical or electrochemical path of reactions.
The chlorine content was measured using Oxygen Flask analysis by subjecting the sample to combustion in an oxygenated flask containing water, followed by shaking; in which chlorine dissolved in water forming HCl solution, the latter solution was titrated with 0.02 M Hg2NO3 to obtain the percentage of chlorine.
The thermodynamic electrochemical windows of water, dissolved nitrogen and chlorine anions were analyzed on the basis of the Pourbaix diagram.
The method is applied to the determination of absorption spectra of chlorine dissolved in different organic solvents and the general feasibility is proven.
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