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The mechanism for the dissolution of Fe is reported by some authors [67].
From the figure it can be realized that enhanced dissolution of Fe takes place due to the strong coordinating tendency of citrate ion with ferrous ions.
Sulfate ions could also complex with Fe(II), and increase the dissolution of Fe(II) from the magnetite structure [7, 41].
In summer, when the pore waters are sulfidic, AEF concentrations are at their lowest, presumably due to either chemically- or microbially-mediated reductive dissolution of Fe(III).
Second, anoxic conditions at the end of winter caused reductive dissolution of Fe (hydr oxides along with a release of MRP.
At sufficiently high chloride concentrations (≥50 mM) only the electropolishing state dissolution of Fe emerges out of its passive state.
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These associated adsorbed and co-precipitated As might be released due to reductive dissolution of Fe-oxide and oxyhydroxides in groundwater.
However, an abrupt decrease in the pH and changes in the redox conditions may cause the dissolution of Fe-Mn nodules and subsequent release of contaminants into the soil system.
We believe that the high reactivity of biogenic magnetite is linked to its high organic carbon content (EPS and other cell-derived biomolecules) as organic molecules have previously been linked to electron shuttling and reductive dissolution of Fe-minerals [11 15].
The transpassive dissolution of Fe-25%Cr, Fe-25%Cr-5%Mo and Fe-25Fe-25%Cr-10Cr-10 in 1 M H2SO4 was studied with a combination of electrochemical techniques conventional and rotating ring-disk voltammetry, impedance spectroscopy and the d.c.
At least 1 2 days before analysis, groundwater and river samples stored in acid-leached scintillation vials were acidified to 1% HCl (Optima, Fisher Scientific) to ensure re-dissolution of Fe oxhydroxides that might have precipitated.
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