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However, the loop-turn and disordered components in the FTIR spectrum (i.e., ∼45% combined in Table 1) are somewhat lower than the roughly-corresponding turn, bend and random coil conformations (i.e., ∼56% combined in Fig. 4B) predicted in the "100 nsec" model.
Both ordered and disordered components exist in a mixed phase but, the former are found in bimolecular crystals whereas the latter correspond to precursors of the ordered forms.
Supramolecular assemblies, which are often formed as a result of spontaneous organization of inherently disordered components into stable organized structures, are ubiquitous in nature and have been subjects of investigation in numerous biomimetic architectures.
According to the structural analysis, 22 these provide a solvent-accessible volume of 60.2 and 47.2 [48.5]%% of the total volume of 1 and 2 (disordered components A[B]), respectively (3232.2 and 2642.4 [2711.0] Å per unit cell at 100 K; see Table S9 in the Supporting Information for further details).
In this case, the two disordered components are shown with red and green bonds and atoms on opposite sides are restrained using asymmetric similarity restraints (right).
Self-assembly is a spontaneous and reversible process in which disordered components are hierarchically organized into structures or patterns due to specific, noncovalent interactions with the components themselves.
Similar(50)
The disorder components were restrained to have similar bond distances and angles.
The occupancy of the disorder components was refined competitively, converging at ratios of 0.634 6):0.366(6) and 0.56(2):0.44(2), respectively.
As an example, consider an n-butyl substituent coordinated through atom C1 that splits into two disorder components at C2. Atom C1 is then in PART 0, C2 A, C3 A and C4 A in PART 1, and C2 B, C3 B and C4 B in PART 2. Atom C1 is bonded to both C2 A and C2 B but, because these two atoms have different PART numbers, H atoms will be generated correctly using the HFIX instruction.
We believe this is due to the disease disorder component, which failed to recognize CAD risk factor effectively.
However, two items of the ADHD including "Often has trouble organizing activities" and "Often runs about or climbs when and where it is not appropriate" are loaded in the oppositional defiant disorder component rather than ADHD component [ 20].
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