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Using over 60 this class of chelating carboxamide ligands, the stereochemical properties of over 150 discrete coordination complexes, studied by single-crystal X-ray crystallography have been analyzed.
Using over 120 pyrazole-based chelating ligands, the stereochemical properties of over 110 discrete coordination complexes, studied by single-crystal X-ray crystallography were analysed.
The technique of combining polypeptide molecules and discrete coordination compounds thus makes it possible to design flexible, reversible, and spin-controllable metastable systems.
From the electron paramagnetic resonance of a Cu2+ probe ion implanted in these materials it was determined that the variation in the compressive moduli with Bloom indices results from a gradation in the relative weightings of two discrete coordination configurations.
Discrete coordination compounds and coordination polymers are topical research fields in inorganic chemistry, crystal engineering, solid-state chemistry, and materials science, due to their potential applications in adsorption, separation, catalysis, electrical, magnetic, and optical applications.
However, Adams (2001 ▸, 2014 ▸) used the concept of bond softness to argue for the consideration of higher coordination shells in the determination of bond-valence parameters (which he calls softBV parameters) for use in dynamic situations where the use of discrete coordination number is not continuously applicable (e.g. ionic conduction; Adams & Prasada Rao, 2014 ▸).
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Complex 1 shows a 1-D fishbone-like supramolecular array via strong aromatic stacking interactions between the discrete mononuclear coordination motifs, whereas 2 has a 2-D layered host coordination framework with the inclusion of bipy and water guests in the cavities.
Novelty, aesthetic appeal and the promise of a wide range of applications drive the current surge of interest in discrete metal organic coordination complexes.
We develop a discrete-event coordination strategy that plans collisionfree transitions between arbitrarily defined formations.
A design strategy is proposed for a two-layer modular discrete-event coordination controller applied to a class of automated manufacturing systems (AMS).
A synthesis approach is proposed for discrete-event coordination architectures applied to a class of automated manufacturing systems (AMS) in which a clear separation is established between equipment control activities and product manufacturing procedures.
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