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Optimal design variables, for the best combinations of the thermal and mechanical performances – the panel geometry and the discharge density – are examined by the analytic and numerical means.
The as-prepared NiHCF/P4VP-g-MWCNT hybrids can possess a huge specific capacitance up to 1035 F·g−1 at a discharge density of 0.05 A·g−1.
In particular under the considered loading conditions, the solution of the optimization problem with all constraints exists only for the enough high discharge density due to the thermal buckling of the web elements inside the panel under non-uniform heating.
It is shown that the high discharge density in the cooling system may be necessary not only for the thermal protection, but also to provide the strength of the panel elements.
When used as a catalyst in a home-made Al air battery, it shows a stable discharge voltage of 1.47 V at a discharge density of 50 mA cm−2, a little higher than that of Pt/C (1.45 V).
Appropriate control of discharge density (by tuning HiPIMS/DCMS power ratio), gas phase composition and energy of the ionized depositing species leads to a route capable of providing ten-fold increase in the deposition rate of a-C film growth compared to HiPIMS Ar discharge (Aijaz et al., 2012).
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Increasing the discharge current density and charge/discharge cycling current density decreases the discharge capacity, but a high charge/discharge cycling current density increases the cycle life of the hydride electrode.
It was found that the hydrogen evolution rate is low below 30 °C with low discharge current density and the discharge current density is high over 30 with high hydrogen evolution rate.
Using these electrocatalysts for the air cathode, we develop primary and rechargeable Zn-air batteries with significantly reduced ORR and OER overpotentials, and thus a high discharge power density of ~265 mW cm−2, and a large energy density of >700 Wh kg−1.
The average discharge power density was 19.6 mW cm−2 at a constant current density of 40 mA cm−2 with an average voltage efficiency of 33%.
Also Cαβopt increases with increasing discharge current density.
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Justyna Jupowicz-Kozak
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