Sentence examples for diminished reaction rate from inspiring English sources
Pleasingly a non-spirocyclic substrate possessing N-ethyl and 4-methyl substituents underwent cyclization with equally high diastereo- and enantiocontrol (96%% ee) but at a marginally diminished reaction rate (entry 9).
Excessive light scattering by the suspended particles also has a progressively diminishing influence on the reaction rate.
These results indicate that the 9-fold lower PRODH activity of D778Y does not diminish the overall PRODH P5CDH reaction rate of this mutant, which is consistent with the channeling assays depicted in Figure 2. To further corroborate impaired channeling activity in the D779Y mutant, single-turnover experiments were performed anaerobically without an electron acceptor for the flavin cofactor.
This variance is dramatically diminished when rint increases to two orders of magnitude below the mean value of the disordered reaction rate (Figure 3c). Figure 4 summarizes the variances resulting from several trial cases.
It is also suggested that an increase in the electrolyte acidity diminishes the overvoltage during discharge but leads at the same time to a more heterogeneous reaction rate distribution on account of the faster kinetics of PbO2 dissolution.
Degradation of metronidazole followed the pseudo-first-order kinetics, and the observed reaction rate constant (kobs) could be improved with increasing nZVM dosage, as well as with diminishing initial metronidazole concentration and pH.
Although reaction rate increased with the addition of hydrogen peroxide, higher levels of hydrogen peroxide had a diminishing return since the excessive hydrogen peroxide could act as a scavenger for the hydroxyl radicals.
Its usability and utility do not diminish with large systems as the algorithmic complexity for a given system is independent of the number of unknown reaction rate parameters.
5. Reaction Rate Fundamentals (Chemical Kinetics).
Reaction rate, the speed at which a chemical reaction proceeds.
