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Sixty seven contiguous axial slices aligned to the anterior commissure posterior commissure (AC-PC) line were collected in 32 gradient directions with b = 700 s/mm2 and one acquisition without diffusion sensitization (B0 image).
A single coherence transfer pathway is selected using an asymmetric set of gradient pulses, and both diffusion sensitization and convection compensation are built into the gradient coherence transfer pathway selection.
Diffusion sensitization was only performed along the slice direction to keep the overall acquisition time low [22].
It involves acquiring a series of diffusion-weighted images, each corresponding to diffusion sensitization along a particular gradient direction.
Sixty-four diffusion-weighted images (b =1300 s mm−2) with distributed diffusion sensitization directions and seven images with no diffusion gradients were acquired.
Diffusion sensitization gradients were applied in three orthogonal directions with the following physical gradient combinations: [1 0 0], [0 1 0], [0 0 1].
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Moreover, the same group recently reported that sensitization by diffusion in a thin film can be more effective than intramolecular sensitization for sensitizer concentrations higher than 5 mM.
The improved wettability of TiO2/HgS after sensitization is helpful for the diffusion of electrolyte and charge transport at the interfaces between photoanode and electrolyte [12].
Bimolecular sensitization is achieved through diffusive encounters.
We also show that when the bilayer undergoes a melting phase transition, or when it is fluidized by benzyl alcohol, the sensitization efficiency decreases because of the enhanced diffusion of singlet oxygen.
The sensitization kinetics of this bimolecular process were found to be nearly diffusion-controlled both in solution (kq = 1 4 × 10 M–1 s–1; in acetonitrile or methanol) and on the chip.
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