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Using PITT technique, the various shapes of the Cottrellian diffusion plots, It1/2 versus log t, were studied as a function of the electrode potential for the Li ions insertion into graphite electrodes.
Traditional posturography analysis and 4 nonlinear time-series analyses (sway density plots, diffusion plots, recurrence quantification, sample entropy analyses) were applied to the recorded CoP time series, based on which 13 traditional and 32 nonlinear time-series CoP-based measures were calculated.
The multilinearity in the shape of the intraparticle diffusion plots has also been observed.
However, pseudo-first-order and intraparticle diffusion plots have poor coefficient of correlation (Table 7).
Open image in new window Fig. 8 Intraparticle diffusion plots for AO8 and AV7 dyes on AFC.
The kinetic studies vis-à-vis pseudo first-order, pseudo second-order, Elovich, Fractional power, intraparticle diffusion plots are shown in Figs. 7, 8, 9, 10 and 11, respectively.
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Intra-particle diffusion plot indicated the complex nature of EE2-charcoal sorption system involving both boundary layer and intra-particle diffusions.
The intercept of the intraparticle diffusion plot (mg/g).
Open image in new window Fig. 8 Intraparticle diffusion plot for FA (a) and intraparticle diffusion plot for AA (b) Table 4 Intraparticle diffusion model FA AA Step Kid (mg g−1 min−1/2) C R 2 Kid (mg g−1 min−1/2) C R 2 1 0.109 −0.022 0.945 0.121 −0.168 0.873.
Open image in new window Fig. 8 Intra-particle diffusion plot for mixed azo dye adsorbed onto spent R. arrhizus biomass.
A single linear profile was obtained for the intraparticle diffusion plot of UMRH-RhB system and R 2 value ranged between 0.8509 and 0.9590.
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