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The 'cell-impedance controlled diffusion' constraint is used in the second model (MII) together with the diffusion equations and boundary conditions.
It is shown that the 'cell-impedance controlled diffusion' constraint used in model MII does not work very well when a large potential step is applied on the electrode.
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To constrain the evolution, an energy function is designed based on two diffusion constraints.
Starch-based scaffolds can diminish diffusion constraints and mechanically stimulate the marrow stroma cells to develop the bone-like mineralized tissue (Gomes et al. 2006).
This is a likely consequence of restrained diffusion constraints due to the vicinity of two out of the three protein partners.
Ti-IPC-1PITi was the most active catalyst in cyclooctene, norbornene, and linalool epoxidation due to the lowest diffusion constraints and sufficient titanium content.
Incorporating a network of microchannels in the interior of the scaffold which may permit the flow of nutrient-rich media has been proposed as a method to overcome these diffusion constraints.
The benefits of introducing secondary mesoporosity through demetallation in alkaline media are remarkable for medium-pore ZSM-5 due to the alleviated diffusion constraints, while the enhanced performance of hierarchical faujasite is less pronounced, but still appreciable.
Nevertheless, in the case of longer wires, the increment in resistance at high cycling rates due to diffusion constraints is more significant.The previous statements can be corroborated when observing the percentage of the capacity obtained galvanostatically during the galvanostatic/potentiostatic cycling.
Diffusion constraints (De=8.0×10-10 m2/s) theough the bead material (1.5% alginate +98.5% H2O) are not severe and are reported as being approximately 85 90% of the diffusivity measured in water (Shishido et al., Chem. Engng. Res. Design: Trans. Inst. Chem. Eng. 73 6), 719 725, 1995; Oyaas et al., 1995a Biotechnol.
One can hypothesize that the resistance of the RD5PR2 biofilm for phage infection and subsequent degradation in comparison with the high planktonic susceptibility can be explained by diffusion constraints within the biofilm.
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