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In an electrochemical system, ion transport near ion exchange membranes or electrodes induces inevitable concentration polarization (i.e., formation of diffusion boundaries), which impedes the mass transport and worsens the energy efficiency.
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Lowering the arsenic overpressure increases the diffusion to form a 'square' diffusion boundary.
EIS study also showed that the resistance of diffusion boundary layer decreased due to mechanical stirring.
The green, blue, and red parts represent GDs, GaAs, and the diffusion boundary, respectively.
The microscopic diffusion boundary layer (DBL) lengths observed in the microchannel are also efficiently characterized from the impedance spectrum.
In the present work, the STAR-CCM+ software is used with a diffusion boundary layer condensation model.
In this work, the FEM is used to solve uncoupled mechanical-water diffusion boundary problems.
Parts of the Ga adatoms diffuse beyond the GD boundary and bond with As atoms nearby, defining the outer outline composed of the diffusion boundary.
According to our model, the effects of diffusion boundary layers on the growth rate are significant.
EIS spectra showed that the resistances from electric-double layer and diffusion boundary layer were the main resistances not the membrane's resistance.
The electric-double layer and diffusion boundary layer resistances of the AEMs were much larger in the 10 mM PB electrolyte, compared to 100 mM PB.
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