Sentence examples for differences in the coordination from inspiring English sources

The compounds show significant differences in the coordination modes and different nuclearity, leading to the formation of mononuclear and tetranuclear structures.

It would arise from the guest water aggregates and would depend on the very slight differences in the coordination chemistry of the Ni II) and Co II) centers.

A comparison of the spectroscopic and photophysical data for the Eu complexes shows that the differences in the coordination geometries of the metal atoms in the Eu pivalates have no effect on intensity of Eu3+ ion luminescence.

Differences in the coordination chemistry associated with Mo6+ were observed which motivated to perform free energy calculations upon MoO3 as a central coordination unit for different metal-to-ligand complexes (1 1, 2 1) in order to characterize the thermodynamically most stable complex at optimum reaction pH.

However, if the pain in the thoracic spine were responsible for changes in coordination, we expected there to be differences in the coordination patterns of C7-T8 and C7-sacrum in the control and case subjects.

There is a little difference in the coordination mode between the low and high Cu2+ loading samples, probably because there are still some adsorption sites in the low Cu2+ loading sample (233 mmol/kg), resulting in the shift of some sorbed Cu2+ in the monodentate mononuclear (MM) complex to the bidentate binuclear (BB) complex, a more stable geometric structure.

The only difference in the coordination of this water molecule, relative to that seen in the S236A·MgPPi complex, is the additional hydrogen bond to the conserved water molecule that is absent in the open conformation.

Despite the differences in the primary coordination spheres, all three redox centers employ noncovalent secondary coordination interactions in fine-tuning the redox properties.

In this case, C h (CET = 2.7 nm) was comparable with C i (approximately 1-nm native SiO2) and the frequency dispersion effect was attributed to losses in the interfacial layer capacitance, caused by interfacial dislocation and intrinsic differences in the bonding coordination across the chemically abrupt ZrO2/SiO2 interface.

Therefore, factors other than the differences in the ligand coordination are most likely to be involved to account for the reduction potential difference.

There are also some differences in the exact coordination spheres of the surface sites, providing a further rationale for the asymmetry that led to the space group transition upon Zn II) binding.