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FTIR analysis of the exhaust for n-heptane, the conventional diesel surrogate, and the GTL diesel surrogate revealed that LTHR produces high concentrations of aldehydes and CO while producing only negligible amounts of CO2.
A reasonably designed diesel surrogate is proved to be an effective way to study the fundamental combustion mechanism of diesel fuel.
The final skeletal mechanism for the diesel surrogate fuel consists of 70 species and 220 reactions without considering cross reactions of the fuel components.
To that end, a potentially lower cost ruthenium substituted pyrochlore catalyst (LSRuZ) was compared to a traditional supported Ru/γ-Al2O3 catalyst in the partial oxidation of a diesel surrogate fuel.
A diesel surrogate fuel model was developed by including n-decane, iso-octane, methylcyclohexane (MCH), and toluene, which represents the n-paraffins, iso-paraffins, cycloalkanes, and aromatic hydrocarbons in diesel fuel, respectively.
Then, a decoupling methodology was employed to construct a skeletal oxidation mechanism for the diesel surrogate model, in which the oxidation of small molecules is described in detail, while extremely simplified mechanisms are used for the oxidation of large molecules.
Similar(47)
Soot formation is compared in turbulent diffusion flames burning a commercial Diesel and two Diesel surrogates containing n-decane and α-methylnaphthalene.
Renewable diesel surrogates made from shorter chain length fatty acids have improved cold flow properties.
Tetralin (1,2,3,4-tetrahydronaphthalene 1,2,3,4-tetrahydronaphthaleneound found is diesel fuels and a candidate component widely used in diesel surrogates.
Therefore, in this study, a methodology to construct diesel surrogates with C10 ∼ C18 hydrocarbon components based on fuel properties and engine combustion and emissions characteristics was proposed.
However, most existing diesel surrogates mainly adopt light hydrocarbon components, increasing the difficulty of accurately reflecting the physical and chemical properties of practical diesel fuel or the combustion and emissions characteristics of diesel engines.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com