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The real time variation of the macroscopic dielectric decay functions with crystallization time has been interpreted assuming an increase in the intermolecular cooperativity of the α relaxation as the polymer chains are obliged to move between crystalline regions.
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When light passes through such structures, SPPs propagate along the metal-dielectric interface, decaying exponentially along the direction perpendicular to the propagation.
By calculating the quantum efficiency as a function of shell thickness, we discuss in detail the quenching mechanism based on SPR-induced non-radiative decay of the dielectric shell-coated gold nanospheres.
Surface plasmon polaritons (SPPs) are surface waves that propagate along the boundary surface between dielectric and metallic materials with fields decaying exponentially in both sides, thereby creating the subwavelength confinement of electromagnetic waves [1].
The third scenario (dielectric shielding) predicts quick rise and quick decay for the moving-charge case.
It is found that the longer propagation distance due to the smaller dielectric constant is accompanied with a larger decay length into the dielectric.
These two parameters can be related to the first two decay parameters k1,2 of the dielectric response modes of the bulk system, and can be determined using constraints of k1,2 from statistical theories.
Field components of the plasmon modes take their highest values at the interface and exponentially decay into the metal and dielectric media.
As can be seen in Figure 6, QDs on the VO2 film exhibit higher PL decay rate than that on the dielectric substrate irrespective of temperature.
As the incident wavelength increases, the decay rate of the free electrons of the dielectric constant of the silver increases, shortening the life of the plasma and broadening the plasma resonance band [34].
Two sets of decay curves are shown for QDs deposited on the dielectric and VO2 film.
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