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The inhibiting effect of competitive adsorption between fresh and cycle oil on desirable reactions aggravates the product distribution.
As the major players in metabolic pathways, enzymes drive the desirable reactions but also regulate metabolic pathways positively or negatively to maintain the energy homeostasis within the cells.
The characteristics of solvent mixture such as functional groups and speciation govern the reactivity of substrate towards desirable reactions and stability of HMF and intermediates against side reactions.
Methods for the synthesis of chiral alcohols and amines have been particularly successful, along with the creation of non-natural activities for such desirable reactions as cyclopropanation and esterification.
We highlight that the ratio and strength of Brønsted and Lewis acid in bifunctional catalyst are critical for maximizing HMF production by selective improvement in the kinetics of desirable reactions (hydrolysis, isomerization, and dehydration) over undesirable reactions (rehydration, polymerization).
Enzymes are crucial to metabolism because they allow organisms to drive desirable reactions that require energy that will not occur by themselves, by coupling them to spontaneous reactions that release energy.
Similar(53)
There any combination of three basic functions is carried out: (1) separating the many types of hydrocarbon present in crude oils into fractions of more closely related properties, (2) chemically converting the separated hydrocarbons into more desirable reaction products, and (3) purifying the products of unwanted elements and compounds.
Among the various organic transformations, the direct addition of N H bonds to alkenes and alkynes is a challenging and highly desirable reaction [2].
The superiority of low temperature Such desirable reaction behavior of the VT(3+) catalyst is attributed to the formation of highly coordinated polymeric vanadyl species on the sample.
Briefly, after finishing the sulfidation process, the feedstock was switched at 220 °C and the desirable reaction pressure and temperature (340 °C), liquid hour space velocity (0.6 1.2 h−1) and H2/oil volume ratio (400 N L/L).
In this study, the structural effects of amines on the kinetic competition among three typical products (carbamates, carbamic acids and bicarbonate) from amines + CO2 were investigated, in contrast to previous thermodynamic studies to tune the reaction of amines with CO2 based on desirable reaction enthalpy and reaction stoichiometry.
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