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In order to speed up the method, the derivatization procedure was modified to the described solvent composition (see " Solvents, reagents, standards, and materials" section) and a reaction time of 5 min.
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This study demonstrates the application of the solution-diffusion pore-flow fluid-resistance (SDPFFR) model, which is used to describe solvent transfer in pressure-driven membrane separation processes.
To account for the solvation effects during receptor-ligand binding, the Born continuum implicit solvation model was chosen as it has been shown to appropriately describe solvent interactions [66].
A quantitative model for the kinetic solvent effect (KSE) was developed by Litwinienko and Ingold, using the H-bond empirical parameters of Abraham et al. Warren and Mayer complemented the use of the Marcus cross-relation with the KSE model to describe solvent hydrogen-bonding effects on both the thermodynamics and kinetics of HAT reactions.
Described solvent-free formation method of nonwovens from the tin-free PLGA results in biomaterials with higher biocompatibility, what is particularly important for their applications.
Thus, it can be seen that we described the solvent effects on the thermodynamic values of this interaction using QM and MM methods.
They described the solvent effect on the reaction kinetics by empirically correlating the experimentally-observed apparent rate constants with the dielectric constants of the different reaction mixtures.
In a similar fashion as described above, solvents containing CO2 were analyzed by plotting overall oil-recovery factor versus the percentage of methane that had been substituted with CO2.
We describe two solvent systems, the first of which meets the first requirement, but the second only partially.
Principal component analysis proved that the only one parameter (mean eluotropic strength) is satisfactory to describe the solvent property, as it explains almost 90% of variance of retention.
Finally, the mobile phase that provided the best resolution and which was used for all analyses described consisted of: solvent A, 0.1% formic acid and 5 mM ammonium formate in water; and solvent B, 100% acetonitrile and 0.1% formic acid.
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