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The final design of the Z-scheme is typically classified into one of two types depending on the electron mediator material: redox ion pairs and electron-conducting metals.
Thus, depending on the structure of the system (and, in particular, depending on the electron donor acceptor distance), the PT is electronically adiabatic or nonadiabatic.
The third term, depending on the electron effective mass, also has a smaller dependence on T than the other terms.
The absorption maxima of the synthesized star-shaped chromophores in thin film are varied from 366 nm to 527 nm depending on the electron donating/accepting properties of the terminal groups.
Under negative polarization, depending on the electron withdrawing effect of the N-chloroalkyl group on the N-H bond, two types of PIL behavior followed the region of EDL charging: hydrogen chemisorption onto AC or direct electrolyte decomposition.
The channel resistance varies by more than two orders of magnitude depending on the electron concentration.
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The luminescent color varied depending on the type of electron-donating group, and the emission color could be controlled from blue to yellowish-green depending on the electron-density distribution induced by electron-withdrawing pentafluorophenyl and electron-donating amino moieties.
When positive and negative voltages were applied, the PIs demonstrated two different types of unipolar memory behaviors (volatile static dynamic random access memory and nonvolatile write-once-read-many-times memory) with a high ON/OFF current ratio up to 108, depending on the electron-accepting and donating substituents of the TPA units.
The apparent Km values for NADH and NADPH vary from about 17 to 258 μM depending on the electron-acceptor used, which is in the range previously observed for prokaryotic NADH quinone oxidoreductases [ 4, 37, 38].
They also correlate, as discussed below, with the fact that these elements are metallic, for that property depends on the ready loss of electrons.
Firstly, it describes the non-local field dependence of the kinetic coefficients which now depend on the electron temperature rather than on the electric field as in the case of the DD model.
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