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Despite the presence of un-reacted [13N]NH3 and radioactive by-products in the crude reaction mixture, the desired 13N labelled Ugi product could be easily isolated using semi-preparative HPLC, as demonstrated for reaction 1.
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Here we show that by utilizing a solid state pn-junction for charge separation and a catalyst deposited on the surface, the efficiency is significantly improved and photocurrents of 6 marem2 are demonstrated for the reduction reaction in the configuration of a photo-electrochemical cell.
We further found stability and robustness of the reactors over prolonged periods of time demonstrated for this example reaction using catalyst 1 for more than 122 reactor volumes and more than 100 hours of continuous operation (Fig. 3b).
The model takes into account conservation of mass, momentum, species and energy coupled with chemical kinetics, and is demonstrated for a three-way reaction mechanism for treatment of automotive exhaust.
We have demonstrated for the minimal chemical reaction system with Hopf bifurcation [ 33] that it is accessible for detailed mathematic-analytical examination [ 54] and a good example system for thermodynamic considerations [ 55].
In addition, superior catalytic performance compared to ionic hydrophilic ligands was demonstrated for important C C coupling reactions such as the Suzuki, Heck, and hydroformylation reactions.
Importantly, the highly efficient catalytic property of the as-obtained Pd-Fe3O4/rGO catalyst was demonstrated for the Suzuki-Miyaura coupling reaction and Mizoroki-Heck coupling reaction.
Recent success in using electrospun nanofibers as supports for metal nanoparticles has been demonstrated for a number of reactions [22, 23].
The dependence of electrocatalytic effects on the structural properties of two-dimensional (2-D) metal adsorbates formed by underpotential deposition (UPD) of Pb, Tl and Bi on gold and silver single crystal faces of (111), (110) and (100) orientation is demonstrated for various electro-reduction reactions in acid solutions.
The performance of our approach is demonstrated for an application to chemical reaction kinetics.
The specificity of this reaction was demonstrated for all subtypes of influenza A (H1 H15, N1 N9) and all subtypes of influenza B. Samples with a positive test result in the first PCR were analyzed in a second PCR with influenza (H5N1)–specific primers and probes.
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