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At the temperature range beyond 70 K, non-radiative delocalization process tends to dominate both fast and slow decay.
Therefore, the observed NMR should result from the quantum interference feature in the strong localization regime, which is different from the T-induced delocalization process.
The deep localized states showed better resistance to the competitive non-radiative process than shallow states because the higher activation energy is needed for the delocalization process.
The slow radiative PL from deep localized exciton recombination suffered less suppression from non-radiative delocalization process, for the higher requested activation energy.
Employing a density matrix formalism for the system coupled to a bosonic thermal bath, we study the interplay between disorder and thermalization, focusing on the delocalization process.
In the region of high PL temperature, the thermal redistribution decreases exponentially and tends to cancellation as from 150 K it starts the delocalization process and the return to band-to-band transitions.
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Electron delocalization processes around the Eu cations are induced by the reaction, as proved via the evolution of the Mössbauer parameters.
Together, these results support our hypothesis of electron delocalization processes as a predominant factor of controlling the dramatic shift of ΔλLSPR.
We are actively working to understand possible charge transport and/or electrons delocalization processes that could result in further improvement in the sensing ability of our LSPR-based sensors.
The characteristic temperatures (T loc/deloc and T escape) are indicated with respect to the localization-delocalization process Fig. 11 Arrhenius fitting of the investigated sample.
Increased DASPMI fluorescence under conditions that elevate the mitochondrial membrane potential has been attributed to uptake according to Nernst distributions, delocalization of π-electrons, quenching processes of the methyl pyridinium moiety, and restricted torsional dynamics at the mitochondrial inner membrane.
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