Sentence examples for delocalization into from inspiring English sources

The resulting carbanion is stabilized by delocalization into the PLP cofactor as well as by delocalization into the OAS carboxylate which forms multiple hydrogen-bonding interactions with the enzyme (backbone amides of Asn81 and Thr82, OH of Thr82).

Generation of the truncated form of EGFR receptors as well as its delocalization into cytoplasmic vesicle may delay proliferation and induce cytotoxicity in DU145 cells.

This model also predicts that the Cα carbanion, generated after thiocarboxylate addition, is stabilized by delocalization into the cofactor as well as by delocalization into the Cβ carboxylate, which forms hydrogen bonds with the amide NH and the side chain OH of Thr82 and with the backbone nitrogen atom of Asn81.

α, β-Elimination mechanisms generally proceed via a quinonoid intermediate, in which the carbanion formed upon abstraction of the C α-proton is stabilized by delocalization into the pyridinium ring of PLP.

These observations and DFT calculations illustrate the occurrence of a considerable amount of spin-delocalization into the 2-substituted-thienyl moieties from the 3-oxophenalenoxyl skeletons.

π-Delocalization into enolone fragment was determined from π-delocalization index λ Q calculated with Equations 1, 2, 3 and 4, using the experimental determined bond distances [43].

For the decrease in spin density at the 2-position by invoking spin-delocalization into the 2-substituted π-systems, we have designed 2-thienyl-3-hydroxyphenalenone derivatives as synthetic precursors of neutral π-radicals, and conducted their oxidation reactions by using a variety of oxidants.

These result in the appearance of positive charges (confirmed by ζ-potential measurements) on the polyelectrolyte chain, which create barriers for radical cations delocalization, their recombination into bipolarons, as well as prevents growth of long PEDOT chains.

Indeed, both acetylation and c-Abl-mediated phosphorylation have been correlated to WRN delocalization from nucleoli into DNA damage-induced foci [ 35, 36], but the mechanism underlying building-up of WRN at fork stalling sites remained elusive.

This is possible, but there is less advantage from electron delocalization in this configuration.

Delocalization of the charge into the phenyl ring resulted in a higher bond order for the inter-ring bond.