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Increases of the local segmental relaxation time, τα, and glass transition temperature, Tg, were observed with decreasing layer thickness.
The fracture toughness of the TiC/CrC multilayer coatings decreased from 4.179 to 1.411 MPa-m12 with decreasing layer thickness.
The nanoindentation hardness of the films increases with decreasing layer thickness.
At larger layer thickness, strength increases with decreasing layer thickness, due to slip confinement to individual layers.
In comparison, Cu/Cr multilayers were prone to a quasi-brittle normal fracture with decreasing layer thickness.
Recovered enthalpy data for aged films (calculated from DSC thermograms) showed that the aging rate in the PS layers decreased with decreasing layer thickness.
Hardness results show that with decreasing layer thickness the strength of ML samples reaches a maximum value and remains relatively constant when layer thickness is less than 100 nm.
The out-of-plane relative electric permittivity (4.1 4.3) increases slightly with decreasing layer thickness 50-255 μm), due to the increased molecular alignment.
A transition of the layered morphology from non-planar interfaces at the submicron level to nearly planar interfaces at the nano-scale was observed with decreasing layer thickness.
The increase of hardness with decreasing layer thickness follows the Hall Petch law for layer thickness greater than about 50 nm, but at lower layer thickness the hardness saturates to a value of about 5 GPa.
Calculated aging rates were also compared with the fraction of interphase material (which increases significantly with decreasing layer thickness), and the decrease in aging rate for films with thinner layers was found to correlate with an increase in interphase fraction.
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