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Particularly, W24 displays a significantly decreased charge recombination rates.
This suggests a larger accumulation of electrons in the heterojunction and reflects decreased charge recombination.
This correspondingly results in a decreased charge trapping and recombination rate, as exhibited from the EIS analysis in Figure 5a.
The significantly decreased charge transfer resistance could benefit for an enhanced cycle life of the SnO2/GNS nanocomposite electrode.
The solvent treated electrodes also showed a dramatically decreased charge transfer resistance from ca. 18,000 Ω to 180 Ω.
Electrochemical results indicate that Li2MoO4 modified Li4Ti5O12/C samples deliver improved rate capability and decreased charge transfer resistance.
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The improved interparticle connectivity, reduced electrolyte decomposition and decreased charge-transfer resistance observed in the Mo-containing samples appear to be beneficial effects of the addition of Mo.
The excellent electrocatalytic performance could be due to abundant active sites, stable chemical property, enhanced exchange current density (J0) and decreased charge-transfer resistance (Rct) of the fabricated MoSe2 nanoflowers.
Our experimental results demonstrate that the electron interaction between Mn and Co, increased electrochemical active area and decreased charge-transfer resistance contribute to the enhancement of the optimized anode in OER performance.
The active area of α-TiP/electrolyte interlamellar interface for charge-transfer reaction increased with the increase in α-TiP content due to the formation of more Emim+-pillared layered α-TiP, which resulted in the improved charge-transfer reaction, thus the decreased charge-transfer resistance Rct.
By virtue of the unique hierarchical nanoarray structure, uniform N-doping and decreased charge-transfer resistance, the as-prepared NCNT array exhibits rather high activity and stability in both ORR and OER, even superior to the mono-functional commercial Pt/C (for ORR) and IrO2 (for OER).
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