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An important point; steric hindrance as in compound BZ4 that have 2-methyl groups on nitrogen atom (N,N-dimethyl) decrease the reactivity.
This kind of production system is more sophisticated than conventional manufacturing chain (as cellular manufacturing system) and can decrease the reactivity time and new products can be quickly introduced (as for dynamic cellular manufacturing system).
This indicates that it's an effective approach to decrease the reactivity of amino groups in triamine by introducing tert-butyl into its ortho-position and HBPIs can be prepared conveniently through the method of 'A2+based based on the principle of unequal reactivity of functional groups.
Methyl groups (mainly in ortho position to the hydroxyl group) decrease the reactivity of the hydroxyl group.
In contrast to the above, substitution of the methyl and isopropyl groups with tertiary butyl groups, which are more electron donating, should decrease the reactivity of the parent compound.
An example of the application of armed-disarmed strategy is to decrease the reactivity of pentenyl glycosides based on torsional effects 72) by the introduction of a cyclic acetal function (disarmed) resulting in chemoselective glycosylation(180) with benzylated pentenyl glycosides (armed).
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Aqel and Panesar (2016) reported that when average particle size of limestone powder decreases, the reactivity of limestone increases.
On the other hand, the conventional drying overnight at 105 °C decreased the reactivity of the sorbent in powder form.
The presence of CO2 decreases the reactivity and selectivity of potassium-containing sample.
The addition of LiPF6 salt significantly decreases the reactivity of Li0.5CoO2 compared to pure EC/DEC solvent.
As the degree of roaming is increased, the ignition delays increased, consistent with the hypothesis that roaming decreases the reactivity of the system.
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