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The results show that the increase of temperature allows the enhancement of mechanical strength, the reduction of water absorption due to the decrease of accessible pores amount and the enhancement of potential contaminants immobilization.
Cellulose microfibril coalescence would be mainly reflected in a decrease of accessible cellulose surfaces, enlargement of LFADs, and the increase of cellulose% crystallinity.
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This increased roughness causes large catalysts to only contact the lumenal surface at small ridges, decreasing the amount of accessible surface area relative to that of samples with smoother lumenal surfaces.
These interactions, that are pH-dependent, then determine an average decrease of the solvent accessible surface.
The calcination of TiO2 resulted, however, in a decrease in its catalytic activity due to extensive dehydration and surface dehydroxylation as well as due to changes of textural properties resulting in a decrease in the amount of accessible active sites.
A considerable number of various zeolite/adsorbate systems show an enhancement of T1 by about one order of magnitude, corresponding to a decrease in the number of accessible Fe3+ ions.
Upon the transition from C10H10O3 (2d) to C6H10O6 (3b), however, both the lesser ability of oxygen to participate in chemical bonding (two bonds for any oxygen instead of four for any carbon) and the decline in available DBEs lead to a drastic decrease in the number of accessible isomers.
However, graphene-based electrodes often suffer from stacking and self-aggregation of graphene sheets due to the strong π-π interaction among graphene layers, which will impede the diffusion of electrolyte, decrease the accessible surface area, and consequently reduce the effective capacitance of the electrodes [17, 18].
We presume that the high affinity and the proximity of the thiophosphorylated intrinsic autoinhibitory domain to the active site result in stable docking of thiophospho-Thr696, reducing the number of accessible active sites (decreasing [E]total).
Number of accessible sites for endoglucanases decreases during hydrolysis.
This can be explained in terms of either saturation of the limited number of accessible active sites on the photocatalyst surface that leads to a decrease in degradation efficiency, or poisoning (deactivation) of the active sites of the catalyst.
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