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While the addition of metallic copper up to 5 g/100 ml progressively decreases the concentration of silver ion in dose-dependent fashion (from 1,000 to 250 μg/ml), further increase in the amount of metallic copper up to 15 g/100 ml does not lead to further increase in the copper ion nor further decrease in the silver ion in the solution [ 64].
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Due largely to a decrease in the amount of silver deposited at the Philadelphia Mint, coinage of silver dollars declined throughout the latter years of the 18th century.
Gradual deposition of silver ion as metallic silver on the surface of metallic copper (step 2, Fig. 1) leads to a gradual decrease in the concentration of silver ion and a concomitant increase in the concentration of copper ion in the solution.
In conclusion, the nanotubes can cause a great decrease in the dimensions of silver nanoparticles, help control their morphology, and prevent them from agglomerating.
The decrease in the extraction of silver ions at a higher concentration of picric acid may be due to a competitive effect between hydronium ions (from picric acid) with silver ions, which causes a decrease in extraction efficiency of silver ions from aqueous phase to organic phase.
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