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Exact(28)
It follows from the calculation that this catalytic effect is related with a decrease in the free cyanide concentration in the diffusion layer at the cathode.
To explore possible solutions to this problem, we discuss quite generally how an overall decrease in the free energy associated with intermolecular binding can originate from different combinations of enthalpic and entropic contributions.
In addition, presumably due to the decrease in the free volume, appropriate annealing (t = 0.5 and 1.0 h) can increase the pitting corrosion resistance significantly of the as-cast alloy.
Upon high-velocity impact, the kinetic energy of the particle led to a decrease in the free energy barrier and an increase in the driving force for the amorphous-to-crystalline phase transformation.
We found that when Asp13, Thr17, Met48, Arg51, and His184 were individually replaced with an alanine in silico, a significant decrease in the free energy of binding for the DehL-l-2-chloropropionic acid model complex was seen, indicating the involvement of these residues in catalysis and/or structural integrity of the active site.
The intercalation of Br into MLG simultaneously increases interlayer separation between the graphene planes, while at the same time giving rise to an increase (decrease) in the free hole carrier density (Fermi energy) because of the transfer of electrons from carbon to bromine.
Similar(32)
Moreover, the decreases in the free T3 to rT3 and free T4 to rT3 ratios distinguished advanced from mild fibrosis, even in individuals with similar serum levels of TSH and free T4.
The degree of crosslinking (the decrease ratio in the free amine group contents of the crosslinked sample to the uncrosslinked sample) of this collagen sponge was approximately 40% [ 12].
Increasing multifunctional content, which increased the crosslink density (with the expected increase in Tg), produced a decrease in the average free volume hole size (Vh) accompanied by a counterintuitive increase in fractional free volume (FFV).
The low shrinkage level for sphere loaded 2-structural systems compared to the pure polymeric counterparts might be explained by the decrease in the structural free energy of the polymeric/particulate 2-structural system.
This could be because of the decrease in the relative free volume in the bottom phase and subsequent decrease in the solubility of the biomolecules [32, 34].
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Justyna Jupowicz-Kozak
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