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However, the m value decreased by 1.7 kcal mol−1 M−1, suggesting a decrease in accessible surface area in the unfolded state.
During the synthesis of these frameworks, the addition of 4,4′-bipyridine as a topological modifier led to the formation of the pto polymorph, which saw 40% less nitrogen uptake than the tbo polymorph, due to a decrease in accessible surface area.
In that case, the gradual decrease in accessible surface area is due to the texture of the boundary of the cell wall, with smaller probes able to reach indentations but never reaching any bottlenecks.
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On the other hand, each of the other three datasets shows dramatic decreases in accessible surface area as catalyst radius is increased.
As new distance constraints are placed in flexible regions, the number of DOF decreases with a corresponding reduction in accessible motion.
stresses that in this case it's actually asking to rezone the superblocks with a net increase, not decrease, in publicly accessible open space, proving the school is trying to do what's right for the neighborhood.
This leads to a charge/discharge asymmetry in the galvanostatic voltage profiles, causing a decrease in the accessible capacity of the particle.
Thermal reduction of GTO/Pt (rGTO/Pt) resulted in rather inferior electrocatalytic responses due to a decrease in the accessible surface area of Pt nanoparticles in the densely stacked graphene layers.
In these clusters, decrease in solvent accessible surface area of the protein on GF binding was calculated.
Notably a conformational change of the catalytic H114 residue side chain and decrease in solvent accessible surface area of the RRR 33 signal residues.
In contrast, sucrose and trehalose are preferentially excluded through a decrease in the accessible surface of the carbohydrate induced by both a steric impediment and an increase in solution surface-tension (20).
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com