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The decomposition of peroxide species is a rate-limiting step.
This result was attributed to the high decomposition of peroxide due to the presence of catalyst.
The cathodic part of the mixed wave was due to the reduction of oxygen (found by the catalytic decomposition of peroxide) to hydrogen peroxide.
Therefore, silica has two roles affecting kinetics of peroxide vulcanization of EPDM: physical effect on the rate of crosslinking reaction through reduced dynamics of rubber chains and catalytic effect on the decomposition of peroxide.
In particular, our Density Functional Theory calculations suggest that Co and Ni atoms embedded into the single vacancies of graphene can activate the O2 molecule and contribute to the decomposition of peroxide.
The high activity and stability of the MnxOy/N-C-3 catalyst is ascribed to its novel hybrid structure, in which MnxOy is a good catalyst for decomposition of peroxide, while N-C not only catalyses the ORR but also prevents MnxOy agglomeration.
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Free radicals (molecular fragments bearing unpaired electrons) that are generated by the decomposition of peroxides or metal alkyls also initiate homogeneous catalytic processes.
The decomposition of peroxides linking the reaction pathway form cyclic chain.
This is due to the sequential decomposition of peroxides of different thermal stabilities distributed in various types of polymeric species.
Peroxiredoxins (PRXs) catalyze the decomposition of peroxides and function in diverse compartments to protect cells against damage from reactive oxygen species (ROS) (Dietz 2003).
Horseradish peroxidase (HRP) is an enzyme that catalyses the decomposition of peroxides and forms free radicals.
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