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The asymmetric reactions with lanthanide complexes had slightly decelerated reaction rates, despite the strong coordination of the Lewis base, compared with the corresponding achiral pathway without the chiral crown ether.
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The addition of Si to Al, which is known to decelerate reaction layer growth in interdiffusion experiments with Al melts, was found to accelerate the reaction layer growth in solid/semi-solid interdiffusion experiments.
This might be due to the fact that the critical phase can be decelerated as deceleration and a prolonged reaction-time is a common feature of older persons [ 36].
The herbicide decays in both treatments informed about the complexation of Fe(III) ions formed from Fenton's reaction, which decelerated S-metolachlor removal.
Mott Schottky plots displays that the carrier density of the oxide film in the transpassive region is decreased by nano-crystallization. Thus, the interfacial reactions are decelerated and the corrosion resistance of the stainless steel in the transpassive region has been greatly improved by nano-crystallization.
Therefore, for hydrogen-selective SCWG process, methanation reaction should be decelerated.
Performing the same experiment with the H103Y variant demonstrated that the mutation significantly decelerated the two-electron transfer reaction from glucose to the redox cofactor (Fig. 4).
Electron-withdrawing groups accelerated the end-capping reaction, while electron-donating groups decelerated it.
In general, titania-based sol gel reaction is very fast and need to be decelerated by the use of suitable chelating agents.
The electroless mechanism is decelerated after deposition of some nanometers of film, hence, a second growth mechanism starts to predominate consisting in the chemical reaction of soluble selenide with hydroxide and Zn2+ cations on the substrate surface.
Nuclear formation can be decelerated in Xenopus extracts, which are commonly used to recapitulate post-mitotic NPC assembly, by reducing the temperature of the reaction (Fichtman et al. 2010).
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