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In parallel, a constant rate was also observed for the decrease of the benzene formation rate itself over the slow deactivation period.
[7], [12] After this short deactivation period, the catalyst maintains its steady-state activity (all values hereafter refer to the steady-state period).
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In contrast to physiological activity, it occurs at transitions from activation to deactivation states, a period of high synchronization.
This zirconium MOF with a manganese porphyrin catalyst shows minimal deactivation over long periods and maintains its structure and high activity after multiple catalytic cycles.
Similar findings have been reported for the DMN and the medial temporal lobe whose magnitude of deactivation (compared to periods of rest) correlates with superior memory ability [48].
However, both catalysts showed slight deactivation during the test period.
And the deactivation catalyst after long period operation can be easily replaced for this kind of microstructured reactor.
A specific type of polymer species, produced during the initial period of deactivation, is proposed to be responsible for the promotion of catalyst activity.
The experimental results indicate that unless the catalyst experiences a very high temperature for a long period, the deactivation is reversible and may be caused by the deposition of carbonaceous compounds on the surface.
Another limitation might be the short resting phase between the n-back blocks which does not allow the investigation of the temporal dynamics of the DMN deactivation during a longer period of time.
Owing to the need to minimize the period of deactivation to ensure recovery recordings could be made, multiple FRAs could not be collected in each condition.
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