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The Raman spectroscopy data of the samples were first analysed using the Tuinstra Koenig (TK) equation.
The results were compared with the measurement data of the samples, and the warpage mechanism was investigated based on the elastic and viscoelastic simulation results.
X-ray diffraction (XRD) data of the samples were recorded using a Bruker D8 Focus X-ray Diffractometer equipped with Cu Kα (λ = 0.15406 nm) radiation.
By the study of XRD and transmission electron microscopy [TEM] data of the samples, it is found that as the Zn concentration increases from x = 0.0 up to x = 0.2, there is no major change in the grain size.
The data of the samples from system II show a very similar pattern, but the COD was on average about three times higher and the VFA/TIC ratio about nine times higher (data not shown).
The analytical data of the samples from the primary digester before, during and after the over-acidification and the second foaming period are shown in Tables 3, 4, and 5.
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Table 1 presents the sociodemographic data of the sample.
Table 2 presents the main biosociodemographic data of the sample.
The operational data of the sampled biogas plants are summarized in Table 1.
Inset in Figure 5d shows the composition and distribution data of the sample mapping.
Demographic and clinical data of the sample are presented in Tables 1 and 2, respectively.
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