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For the evaluation and design of crystallisation processes solubility data of solids in mixtures of a solvent and carbon dioxide is crucial.
The proposed consistency test method can be used with confidence to determine consistency or inconsistency of a set of experimental solubility data of solids in high pressure gases.
A correlation, incorporating the operating conditions of solids circulation rate and superfacial gas velocity has been developed which adequately correlates published data of solids hold-up for fully developed flow.
Spatial and temporal data of solids fractions in a binary mixture are analysed using methodology based on statistical mechanics principles which lead to the definition of 'micro-turbulence' during flow in terms of the local fluctuating volume fractions of individual solid components.
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The use of IGC would be an effective tool to evaluate the physiochemical data of solid materials.
Three-phase equilibrium data of solid (prednisolone)–liquid vapor were obtained from the intersection of the two-phase isopleths vapor liquid and solid liquid.
These simulations were found to be consistent with the experimental data of solid-state NMR, IR, Raman, and X-ray diffraction.
A good agreement is obtained between the experimental data of solid distributions and the simulation results in the flow fields of liquid solid solid as well as liquid solid systems.
A copy of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK [fax: +44 0 -1223-336033 or e-mail: [email protected]. X-ray powder diffraction data of solid 1, 2 and 3 were collected using a PANalytical X'Pert PRO (HTK) diffractometer with CuKα radiation.
(12) The benzoic and fumaric acid cocrystals were stable for several hours and XRPD data of the solids at the end of the experiment confirmed that the form had not changed.
In the case of medium and high volume fractions of solid, the distribution of strain rate is calculated by using compression test data of semi-solid materials (SSMs).
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