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In the present work, it is also investigated how different choices for the lattice site size alter the description of pressure-volume-temperature (PVT) data of polymers.
The expression of a biparabolic model to represent the dielectric relaxation data of polymers is combined with a statistical method (the LEVM6 program) to provide a reasonable estimation of the parameters of this model.
The program was designed upon the difficulty of taking into account all the molecular arrangements that are initially compatible with the experimental diffraction data of polymers, in particular when these consist of chemical repeating units with a wide accessible conformational space.
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Performance data of polymer composite electrodes are also compared with those of high surface area carbon-based composite electrodes.
In that case, using the rheological data of polymer solutions and without the need for costly experiments the operating condition of the process can be analyzed.
Experimental data of polymer behaviour at high strain rates in the literature, mostly obtained with a split Hopkinson pressure bar (SHPB), shows a dependence on the thickness of the specimen.
A model basing on surface energy data of polymer components (rubber and dispersing agent) and filler was introduced in order to determine the thermodynamic equilibrium state of filler wetting, which is found to be simultaneously determined by the filler polymer affinity and the rubber/dispersing agent mass ratio.
The DLS data of polymer solutions are summarized in Table 4.
The plots of P−1/a vs sin2(θ/2) with a = 1.4 and 1.5 were applied successfully to various light scattering data on polymers of large molecular weight more than several million yielding the intercept of unity and correct values of 〈s2〉.
Table 4 Thermoanalytical data of the polymers 36 45 Polym.
Powder XRD patterns and UV vis data of the polymers indicated that the polymer solid was amorphous.
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